General Reaction Table information
Name Description
leavinggroup_pa Gas phase proton affinity of common leaving groups in transphosphorylation reactions for which experimental data is available

Gas phase proton affinity of common leaving groups in transphosphorylation reactions
molecule APA RPA APA' Exp
water
HOH 390.42 0.00 390.30 390.30*
alkyl alcohols
methanol 379.18 0.00 382.00 382.00*
ethanol 376.02 -3.16 378.84 378.20*
1-propanol 374.58 -4.60 377.40 376.00*
2-propanol 374.37 -4.81 377.19 375.70*
thiols
methanethiol 357.27 0.00 357.30 357.30*
ethanethiol 354.96 -2.31 354.99 355.40*
1-propanethiol 354.80 -2.47 354.83 354.20*
2-propanethiol 354.02 -3.25 354.05 353.40*
phosphates
dimethyl hydrogen phosphate 330.13 0.00 331.60 331.60*
phosphoric acid 328.84 -1.28 330.32 330.50*
carboxylic acids
formic acid 342.04 0.00 344.00 344.00*
acetic acid 346.43 4.39 348.39 347.20*
propanoic acid 346.13 4.10 348.10 347.40*
aromatic
phenol 347.65 0.00 350.10 350.10*
p-nitrophenol 323.65 -24.00 326.10 327.80*
o-chlorophenol 342.40 -5.24 344.86 343.40*
m-chlorophenol 339.84 -7.81 342.29 341.70*
p-chlorophenol 341.08 -6.56 343.54 343.40*
p-methylphenol 348.88 1.23 351.33 350.70*
APA = absolute proton affinity
RPA = proton affinity relative to reference value
APA' = corrected absolute proton affinity
Exp = experimental value